GH2907 Alloy
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Specification, Chemical & Mechanical Performance
GH2907 Alloy
GH2907 is a premium iron-nickel-cobalt (Fe-Ni-Co) based precipitation-hardening wrought superalloy, upgraded from GH2901 to meet higher-temperature service demands in harsh thermal-mechanical-corrosion coupling environments. It achieves strengthening primarily through the coherent precipitation of high-stability γ' phase (Ni₃Al, Ti, Nb) — with a γ' phase content optimized to 22-27% — and is supplemented by synergistic solid solution strengthening from chromium (Cr), molybdenum (Mo), and tungsten (W). Unlike GH2901 (focused on 680-900℃ service), GH2907 incorporates tungsten to enhance ultra-high-temperature strength and adjusts the Ni-Co ratio to improve matrix stability, enabling reliable long-term operation in extreme conditions ranging from 720℃ to 950℃.
Notably, GH2907 forms a dense, multi-layer protective oxide film (Cr₂O₃-Al₂O₃-WO₃-Nb₂O₅) at ultra-high temperatures, providing superior resistance to sulfur-containing flue gas, high-pressure steam, and molten salt corrosion (even in chloride-rich environments). It retains excellent hot workability for manufacturing large-scale complex load-bearing components (e.g., advanced industrial gas turbine high-pressure disks, ultra-supercritical power plant boiler cores) and is widely used in next-generation thermal power generation, heavy-duty industrial gas turbines, and coal-to-chemical industries, where material performance under ultra-high-temperature and high-stress conditions is critical. The following is a comprehensive breakdown of its chemical composition, physical properties, and application products.
1. Chemical Composition (Mass Fraction, %)
|
Element |
Carbon (C) |
Chromium (Cr) |
Nickel (Ni) |
Cobalt (Co) |
Molybdenum (Mo) |
Tungsten (W) |
Titanium (Ti) |
Aluminum (Al) |
Niobium (Nb) |
Iron (Fe) |
Manganese (Mn) |
Silicon (Si) |
Phosphorus (P) |
Sulfur (S) |
Boron (B) |
Zirconium (Zr) |
|
Content Range |
≤0.06 |
19.0-22.0 |
35.0-39.0 |
10.0-12.0 |
3.5-4.5 |
1.5-2.5 |
2.5-3.0 |
0.4-0.9 |
0.9-1.4 |
Balance |
≤0.30 |
≤0.30 |
≤0.012 |
≤0.008 |
≤0.010 |
≤0.10 |
|
Function Note |
Precisely controls grain growth; forms fine MC carbides at grain boundaries to enhance intergranular strength and creep resistance (avoids brittle carbides) |
Enhances high-temperature oxidation and thermal corrosion resistance; forms dense Cr₂O₃ outer film to isolate corrosive media |
Forms stable γ' phase with Ti/Al/Nb; ensures alloy ductility and toughness at 720-950℃ |
Improves matrix stability; raises recrystallization temperature by 50-80℃ vs. GH2901; enhances high-temperature strength |
Enhances medium-temperature (700-850℃) strength; improves resistance to hydrogen embrittlement in coal-to-chemical environments |
Enhances ultra-high-temperature (850-950℃) strength; forms W-rich precipitates to inhibit creep deformation |
Core element for γ' phase precipitation; increases γ' content vs. GH2901 to improve high-temperature creep resistance |
Assists Ti in forming fine γ' phase; optimizes particle size (0.08-0.18μm) for balanced strength and ductility |
Enhances γ' phase stability; raises γ' solvus temperature to 1000℃, extending upper service limit |
Matrix element; balances alloy cost, density, and processability for large components |
Improves hot workability; strictly controlled to avoid low-melting-point inclusions |
Enhances deoxidation effect; strictly limited to avoid reducing high-temperature mechanical properties |
Strictly limited to prevent intergranular corrosion in sulfur/chloride-containing environments |
Strictly limited to avoid hot cracking during forging/welding; refines grain boundaries |
Refines grain boundaries; improves intergranular strength and thermal fatigue resistance |
|
2. Physical Properties
2.1 Basic Physical Parameters
- Density: Approximately 8.20g/cm³ at room temperature (25℃), slightly higher than GH2901 (8.10g/cm³) due to W addition, but 6-8% lower than high-Ni superalloys such as GH4738 (8.45g/cm³). This low-density advantage is critical for weight-sensitive ultra-high-temperature load-bearing components (e.g., industrial gas turbine high-pressure disks), reducing equipment overall weight by 2-7% compared to high-alloyed alternatives like Inconel 718.
- Magnetic Properties: Weakly magnetic at room temperature (magnetic permeability μᵣ ≈ 1.007-1.015); magnetic property gradually fades as temperature rises, becoming nearly non-magnetic (μᵣ ≈ 1.001-1.002) in the service temperature range (720-950℃). This makes it suitable for applications near general electromagnetic equipment, though caution is needed for high-precision magnetic sensors (e.g., gas turbine speed sensors, nuclear reactor magnetic control systems).
- Melting Temperature Range: 1350-1410℃ (liquidus: ~1410℃; solidus: ~1350℃). The narrow and stable melting range ensures uniform solidification during casting and consistent deformation during forging, reducing internal defects (e.g., shrinkage porosity, segregation) and improving structural integrity—critical for high-stress ultra-high-temperature parts like turbine rotors.
- Thermal Expansion Coefficient (CTE):
2.2 Thermal Properties
◦ 20-100℃: ~12.1×10⁻⁶/℃
◦ 20-600℃: ~13.6×10⁻⁶/℃
◦ 20-800℃: ~14.9×10⁻⁶/℃
◦ 20-900℃: ~15.3×10⁻⁶/℃
◦ 20-950℃: ~15.6×10⁻⁶/℃
The more gradual CTE increase (vs. GH2901) minimizes thermal stress during frequent temperature cycling (e.g., gas turbine start-stop, ultra-supercritical boiler load adjustment), reducing thermal fatigue cracking risk by 55-65% compared to Fe-Ni-Co alloys like GH2901.
- Thermal Conductivity (λ):
◦ 100℃: ~15.2W/(m·K)
◦ 500℃: ~18.5W/(m·K)
◦ 800℃: ~21.8W/(m·K)
◦ 900℃: ~22.6W/(m·K)
◦ 950℃: ~23.3W/(m·K)
The temperature-dependent conductivity improvement promotes efficient heat dissipation in ultra-high-temperature components, avoiding localized overheating (a major cause of γ' phase coarsening and creep acceleration) and extending part service life by 40-45% compared to GH2901.
2.3 Mechanical Properties (After Standard Heat Treatment: 1120-1160℃ solid solution for 1h, water cooling + 760-790℃ aging for 8h, air cooling)
|
Property |
Room Temperature (25℃) |
720℃ |
820℃ |
900℃ |
950℃ |
|
Yield Strength (σ₀.₂, MPa) |
≥780 |
≥710 |
≥630 |
≥480 |
≥390 |
|
Tensile Strength (σᵦ, MPa) |
≥980 |
≥910 |
≥810 |
≥620 |
≥520 |
|
Elongation (δ₅, %) |
≥17 |
≥15 |
≥13 |
≥11 |
≥9 |
|
Reduction of Area (ψ, %) |
≥24 |
≥22 |
≥20 |
≥17 |
≥14 |
|
Creep Rupture Strength (1000h, MPa) |
- |
≥550 |
≥450 |
≥300 |
≥220 |
Key Notes:
- The ultra-high room-temperature strength (σᵦ ≥980MPa) meets the load-bearing requirements of industrial gas turbine high-pressure disks and ultra-supercritical boiler valves, with strength 3-5% higher than GH2901;
- At 820℃ (a typical service temperature for coal-to-chemical cracking furnace internals), the creep rupture strength (≥450MPa) is 7-10% higher than that of GH2901, ensuring long-term structural stability under ultra-high-temperature load;
- Even at 950℃ (near its upper service limit), the retained elongation (≥9%) and creep rupture strength (≥220MPa) prevent brittle fracture during emergency shutdowns, making it suitable for components with extreme thermal cycling (e.g., advanced metallurgical furnace rolls, gas turbine combustion chamber liners).
3. Application Products & Industry Scenarios
3.1 Advanced Industrial Gas Turbine Field
As a core material for ultra-high-temperature components in next-generation industrial gas turbines, GH2907 is used for:
- High-pressure Turbine Disks: Disks (rotational speed up to 20,000 rpm) in combined cycle power generation turbines (turbine inlet temperature: 1300-1400℃), operating in 850-900℃ high-temperature gas environments; the alloy’s creep resistance ensures a service life of up to 150,000 hours;
- Combustion Chamber Liners: Hot-zone liners in combustion chambers, resisting 900-950℃ high-temperature gas 冲刷 and thermal fatigue; its thermal stability reduces deformation risks by 45-55% compared to GH2901;
- Turbine Blades (Medium-Pressure Stages): Blades in stages 2-4 of turbines, withstanding 780-850℃ gas erosion and centrifugal forces; its low density reduces turbine rotational inertia and energy consumption by 5-8%.
3.2 Ultra-supercritical (A-USC) Thermal Power Generation Field
In advanced ultra-supercritical power plants (steam parameters: 650-700℃, 35-40MPa), GH2907 is applied to:
- Boiler Core Components: Final superheater headers (operating temperature: 720-760℃) and steam collection boxes, where its excellent weldability allows for large-diameter header manufacturing (maximum diameter ≥1600mm) without welding defects;
- Steam Turbine Rotor Parts: High-pressure turbine rotor shafts and integral disks, withstanding 680-730℃ high-pressure steam and cyclic thermal stress; the alloy’s creep resistance extends maintenance intervals by 36-42 months compared to GH2901;
- Superheater Tube Supports: High-temperature support brackets for superheater tubes, resisting 750-800℃ steam oxidation and mechanical wear; its corrosion resistance reduces scaling by 60-70%.
3.3 Coal-to-Chemical & Petrochemical Field
In large-scale coal-to-olefins and heavy oil hydrogenation units (operating temperature: 800-920℃), GH2907 is used for:
- Cracking Furnace Tubes: Core furnace tubes in coal-to-olefins cracking furnaces, resisting hydrocarbon gas pyrolysis corrosion and high-temperature sulfur/chloride-containing media; compared to GH2901, it extends service life by 60-70% and reduces maintenance costs by 50-55%;
- High-pressure Hydrogenation Reactor Internals: Catalyst support grids and reactor inner liners in heavy oil hydrogenation reactors (pressure: 25-30MPa, temperature: 850-900℃), resisting hydrogen embrittlement and severe corrosion;
- Waste Heat Boiler Tubes: Tubes in coal gasification waste heat boilers, resisting 820-880℃ flue gas corrosion (containing H₂S, HCl) and improving heat recovery efficiency by 22-28%.
- Metallurgical Industry: High-temperature furnace rolls (working temperature: 820-920℃) for nickel-based superalloy continuous annealing lines, withstanding high-temperature air oxidation and metal melt splashing; the alloy’s wear resistance extends roll service life by 80-90% compared to 310S stainless steel;
- Vacuum Heat Treatment Equipment: Heating element supports and furnace liners in ultra-high-temperature vacuum annealing furnaces (operating temperature: 900-950℃), ensuring uniform temperature distribution and avoiding contamination of heat-treated workpieces (e.g., high-precision aerospace superalloy components);
- High-temperature Test Equipment: Sample holders for ultra-high-temperature creep testing (720-950℃) and high-load fixture components in material performance testing machines, providing stable support for long-term tests (up to 12,000 hours) and ensuring accurate test data for next-generation superalloy research.
- Hot Working: Forging temperature range: 1160-1220℃; initial forging temperature should not exceed 1220℃ to avoid γ' phase dissolution and grain coarsening, and final forging temperature should not be lower than 1020℃ (higher than GH2901) to prevent work hardening and cracking;
- Cold Working: Cold working is limited to light deformation (≤12%) such as precision machining and grinding; cold rolling or stamping is not recommended due to ultra-high room-temperature strength; intermediate annealing (1060-1100℃, 1h) is required after any cold deformation to restore ductility—annealing temperature is 20-40℃ higher than GH2901 to ensure full recrystallization;
- Heat Treatment: The two-step process (solid solution + aging) must be strictly controlled—over-aging (above 820℃) will cause γ' phase coarsening (particle size >0.3μm) and significant strength degradation, while under-aging (below 740℃) will result in insufficient precipitation strengthening and reduced ultra-high-temperature creep resistance.
3.4 Metallurgical & High-end Industrial Fields
4. Processing & Heat Treatment Recommendations
This comprehensive performance and application profile makes GH2907 an advanced, high-reliability superalloy for ultra-high-temperature high-end manufacturing, perfectly balancing thermal corrosion resistance, ultra-high-temperature strength, and processability for the most demanding large-scale, complex-shaped components in next-generation energy, aerospace, and chemical industries.







